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Selective separation of rare earth metals by solvent ...

Selective separation of rare earth metals by solvent extraction in the presence of new hyrophilic chelating polymers functionalized with ethylenediaminetetraacetic acid. II. Separation properties by solvent extraction

Recent Advances in the Separation of Rare Earth Elements ...

However, the leaching steps are seldom selective, and large amounts of competing elements can be extracted. 16 An additional difficulty arises from the unfavorable distributions (concentrations) of distinct rare earth metals in common ores/minerals. Therefore, supplementary separation and purification steps are required in order to obtain the ...

Tuneable separation of gold by selective precipitation ...

A resulting selective precipitation could both eradicate the use of potentially hazardous organic solvents in SX separations and simplify a hydrometallurgical separation process.

Separation of rare gases and chiral molecules by selective ...

@article{osti_1167294, title = {Separation of rare gases and chiral molecules by selective binding in porous organic cages}, author = {Chen, Linjiang and Reiss, Paul S. and Chong, Samantha Y. and Holden, Daniel and Jelfs, Kim E. and Hasell, Tom and Little, Marc A. and Kewley, Adam and Briggs, Michael E. and Stephenson, Andrew and Thomas, K. M ...

Rare earth separations by selective borate crystallization ...

In the application perspective, since the scheme of selective borate crystallization has been demonstrated to be effective for lanthanide separation in our study, the optimizations on the ...

Highly Selective Separation of Rare Earth Elements by Zn ...

Rare earth elements (REEs) are used widely in devices of many fields, but it is still a troublesome task to achieve their selective separation and purification. Metal–organic frameworks (MOFs) as an emerging porous crystalline material have been used for selective separation of REEs using the size-selective crystallization properties. However, so far, almost all MOFs cannot be used directly ...

Thermodynamics of the Selective Separation of La(III) and ...

This study probed the selective separation of lanthanum and yttrium in a nitrate medium in the presence of aluminum and calcium impurities using di-(2-ethylhexyl) phosphoric acid (D2EHPA). The factors studied in a central composite design (CCD) included extractant concentration, pH, concentration ratio of total impurities to rare earth elements, and interaction of these three factors. The ...

Selective Extraction of Rare Earth Elements from Permanent ...

The yttrium-- rare earth concentrates were obtained from Fergusonite ore, Gadolinite ore, and a by-product from an ion-exchange resin separation process. In each case the mixture in terms of oxide was composed of from 50 to 60% yttrium and 5 to 15% heavy rare earths with the light rare earth fraction constituting the remaining material.

Separation of rare gases and chiral molecules by selective ...

It is shown that a porous organic cage molecule has unprecedented performance in the solid state for the separation of rare gases, such as krypton and xenon, and selective binding of chiral organic molecules such as 1-phenylethanol, suggesting applications in enantioselective separation. The separation of molecules with similar size and shape is an important technological challenge.

Selective separation of rare earth ions from aqueous ...

Separation of rare earth ions (RE 3+) from aqueous solution is a tricky problem due to their physico-chemical similarities of properties.In this study, we investigate the influence of the functionalized ligands on the adsorption efficiency and selective adsorption of La 3+, Nd 3+, Gd 3+ and Y 3+ from aqueous solution using Magnetite (Fe 3 O 4) nanoparticles (NPs) functionalized with citric ...

Selective Separation of Rare Earth Metals by Solvent ...

The selective separation of rare earth metals by solvent extraction including these chelating polymers in the aqueous phase is the goal of this work. The polymers were characterized by IR analysis, elemental analysis, gel permeation chromatography (GPC) measurement, and pH titration. Two kinds of polymers with different solubilities in water ...

Rationally designed rare earth separation by selective ...

A simple, environmentally benign, and efficient chemical separation of rare earth oxalates (CSEREOX) within two rare earth element (REE) subgroups has been developed. The protocol allows for selective solubilization of water-insoluble oxalates of rare earth elements, and results in efficient REE ext …

(PDF) Selective separation of rare earths and impurities ...

A new technique for the selective separation of rare earth oxides and impurities from lower grade titaniferous ores has been developed. The process includes roasting the ore with alkali followed ...

Selective Crystallization of Rare‐Earth Ions into Cationic ...

For rare-earth separation, selective crystallization into metal-organic frameworks (MOFs) offers new opportunities. Especially important is the development of MOF platforms with high selectivity toward target ions. Here we report a MOF platform (CPM-66) with low-coordination-number environment for rare-earth ions.

[PDF] Selective Extraction of Rare Earth Elements from ...

Rare earth elements (REE) are present at low concentrations (hundreds of ppm) in phosphoric acid solutions produced by the leaching of phosphate ores by sulfuric acid. The strongly acidic and complexing nature of this medium, as well as the presence of metallic impurities (including iron and uranium), require the development of a particularly cost effective process for the selective recovery ...

Selective separation of rare earth elements by ion ...

EDTA quantitatively strips the light rare earth from sulfonic resin. This difference in chemical affinity between iminodiacetic resin and EDTA for the heavy and light rare-earth elements gives selective elution two separation equilibriums and may account for the excellent segregation achieved by this resin-eluent combination.

Selective Separation of Light and Heavy Rare Earth ...

Different separation techniques such as solvent extraction, ion exchange, and precipitation are often used for recovery of rare earth elements (REEs) from pregnant leach solutions obtained from acid leaching. Solvent extraction is generally accepted as the most appropriate commercial technology for separating REEs due to the need to be able to handle larger volumes of diluted pregnant solutions.

(PDF) Rare earth separations by selective borate ...

For rare‐earth separation, selective crystallization into metal‐organic frameworks (MOFs) offers new opportunities. Especially important is the development of MOF platforms with high ...

US6093376A - Selective separation of rare earth elements ...

A method is disclosed to separate the heavy rare earth elements Lu through Sm plus Y by an ion-exchange process called selective elution. Mixed rare earths are saturated onto a loading column containing sulfonic resin. Iminodiacetic resin in a separation column is conditioned into the hydrogen and ammonium form before it is saturated with rare earth retaining ion.

CHLORINATION AND SELECTIVE VAPORIZATION OF RARE …

Rare earth elements are part of the lanthanide series in the periodic table. The uses and applications for these elements are ever increasing. Applications vary from smart phones to medical imaging equipment and more. Current separation techniques used today are hydrometallurgically intensive. The

On laser rare-isotope separation (Journal Article) | OSTI.GOV

A brief review on laser separation of rare ytterbium and palladium isotopes by selective photoionisation is presented. The {sup 168}Yb isotope enrichment is performed using the optical scheme proposed by A.M. Prokhorov and co-workers in 1991. The kinetic model of selective photoionisation is ...

Selective separation of rare earths from spent Nd-Fe-B ...

The research presents an effective approach to achieve the selective separation of rare earth elements (REEs) from waste Nd-Fe-B magnets. Investigations show that the use of a two-stage roasting process can significantly reduce the amount of ammonium sulfate required and improve the separation efficiencies of REEs.

Selective extraction and column separation for 16 kinds of ...

Selective extraction and column separation for 16 kinds of rare earth element ions by using N, N-dioctyl diglycolacid grafted silica gel particles as the stationary phase J Chromatogr A . 2020 Sep 13;1627:461393. doi: 10.1016/j.chroma.2020.461393.

Selective separation of rare earths and impurities from ...

A new technique for the selective separation of rare earth oxides and impurities from lower grade titaniferous ores has been developed. The process includes roasting the ore with alkali followed ...

Separation of rare gases and chiral molecules by selective ...

The separation of molecules with similar size and shape is an important technological challenge. For example, rare gases can pose either an economic opportunity or an …

A separation processing for industrial rare earth feed ...

Hydrometallurgy, 2013, 131: 133. [34] Sun X Q, Luo H M, Dai S. Mechanistic investigation of solvent extraction based on anion-functionalized ionic liq- uids for selective separation of rare-earth ions. Dalton Trans., 2013, 42(23): 8270. DONG Yamin et al.,

Selective separation of scandium (III) from rare earth ...

It was reported that at lower acidity other rare earth metal ions could not be extracted by this IL, suggesting that ([A336][P507] was highly effective for the selective separation of Sc (III) from other rare earth metals.

Tuneable separation of gold by selective precipitation ...

3 The efficient separation of metals from ores and secondary sources such as electronic waste is necessary to realising circularity in metal supply. Precipitation processes are increasingly popular and are reliant on designing and understanding chemical recognition to achieve selectivity. Here we show that a simple tertiary diamide precipitates gold selectively from...

Antagonistic Role of Aqueous Complexation in the Solvent ...

Selective extraction of metal ions from a complex aqueous mixture into an organic phase is used to separate toxic or radioactive metals from polluted environments and nuclear waste, as well as to produce industrially relevant metals, such as rare earth ions.

Rationally designed rare earth separation by selective ...

A simple, environmentally benign, and efficient chemical separation of rare earth oxalates (CSEREOX) within two rare earth element (REE) subgroups has been developed. The protocol allows for selective solubilization of water-insoluble oxalates of rare earth elements, and results in efficient REE extraction e

Bridging Hydrometallurgy and Biochemistry: A Protein-Based ...

The extraction and subsequent separation of individual rare earth elements (REEs) from REE-bearing feedstocks represent a challenging yet essential task for the growth and sustainability of renewable energy technologies. As an important step toward overcoming the technical and environmental limitations of current REE processing methods, we demonstrate a biobased, all-aqueous REE extraction and ...

Separation of rare gases and chiral molecules by selective ...

The separation of molecules with similar size and shape is an important technological challenge. For example, rare gases can pose either an economic opportunity or an environmental hazard and there is a need to separate these spherical molecules selectively at low concentrations in air. Likewise, ch …

Recent Advances in the Separation of Rare Earth Elements ...

Over the past decades, the need for rare earth elements (REEs) has increased substantially, mostly because these elements are used as valuable additives in advanced technologies. However, the difference in ionic radius between neighboring REEs is small, which renders an efficient sized-based separation extremely challenging.

US3575687A - Process for the selective separation of rare ...

the recovery of rare earth metal values in aqueous solution by contacting of solution with an organic phase including an organic extractant comprised of a mixture of anionic and cationic extraction agents. the anionic agent is a quaternary ammonium of phosphonium compound and the cationic agent is selected from aliphatic and aryl phosphates, carboxylic acids, organophosphoric acids and oximes.

Selective separation of bovine hemoglobin using magnetic ...

Selective separation of heme proteins and peptides from complicated biological samples before comprehensive identification and characterization of intact biomolecules which are low stoichiometry is indispensable for ongoing proteomics. Here, three magnetic mesoporous rare-earth silicate (rare-earth …

Selective separation of rare-earth metal ions from aqueous ...

The prospects of the electroflotation method for selective separation of rare-earth metal ions (Ce 4+ and La 3+) from aqueous solutions in a flow-type plant are described.The separation process proceeds most effectively in sodium sulfate and sodium nitrate solutions at pH value of 5.0.